Smart Hybrid Materials (SHMs)
مختبر شمس لعلوم النانو
Self-Assembled Nanomaterials for Biomedical, Sensing and Separation Applications

Page 10/12/2018 13:48:19

a new work on Supramolecular organic framework is just accepted in JACs

10/8/2018
 
 
 

Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity


Abstract Image

ChaixArnaud; MouchahamGeorges; ShkurenkoAleksander; HoangPhuong​; MoosaBasem; BhattPrashant M.; AdilKarim; SalamaKhaled N.; EddaoudiMohamed; Khashab, Niveen M. Journal of the American Chemical Society (2018) 140, 14571−14575.
ChaixArnaud; MouchahamGeorges; ShkurenkoAleksander; HoangPhuong​; MoosaBasem; BhattPrashant M.; AdilKarim; SalamaKhaled N.; EddaoudiMohamed; Khashab, Niveen M.
cluster within cluster, inorganic hosts, Lewis acids, polyoxometalates, proton conductivity.
2018
Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.