Smart Hybrid Materials (SHMs)
مختبر شمس لعلوم النانو
Self-Assembled Nanomaterials for Biomedical, Sensing and Separation Applications

Publications 2019

Adhesive supramolecular polymeric materials constructed from macrocycle-based host-guest interactions

X. Ji, M. Ahmed, L. Long, N.M. Khashab, F. Huang, J.L. Sessler. Adhesive supramolecular polymeric materials constructed from macrocycle-based host-guest interactions. Chem. Soc. Rev., 2019, 48, 2682-2697
X. Ji, M. Ahmed, L. Long, N.M. Khashab, F. Huang, J.L. Sessler
Supramolecular chemistry, Self assembly, Host-guest complexation
2019
Nature uses the power of non-covalent interactions as the basis for many kinds of adhesion phenomena. Inspired by nature, scientists have prepared various synthetic adhesive materials that rely on a number of non-covalent interactions at the interfaces. Commonly used non-covalent interactions include hydrogen bonding, π–π stacking, charge transfer interactions, electrostatic interactions, hydrophobic interactions, macrocycle-based host–guest interactions, among others. Within this context, macrocycle-based host–guest interactions are of particular interest. Often they give rise to distinct properties, such as multiple combined noncovalent interactions and a diversity of stimuli-based responsiveness. In this tutorial review, we will summarise recent advances in adhesive supramolecular polymeric materials that rely primarily on macrocycle-based host–guest interactions. An overview of future challenges and a perspective of this sub-field are also provided.