Smart Hybrid Materials (SHMs)
مختبر شمس لعلوم النانو
Self-Assembled Nanomaterials for Biomedical, Sensing and Separation Applications

Publications 2018

Trianglamine-based supramolecular organic framework with permanent intrinsic porosity and tunable selectivity

​A. Chaix, G. Mouchaham, A. Shkurenko, P. Hoang, B. Moosa, P.M. Bhatt, K. Adil, K.N. Salama, M. Eddaoudi, N.M. Khashab. Trianglamine-based supramolecular organic framework with permanent intrinsic porosity and tunable selectivity. Journal of the American Chemical Society 140 (44), 14571-14575, 2018
A. Chaix, G. Mouchaham, A. Shkurenko, P. Hoang, B. Moosa, P.M. Bhatt, K. Adil, K.N. Salama, M. Eddaoudi, N.M. Khashab
Carbon dioxide, supramolecular chemistry, porosity
2018
​Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.