Trianglamine-based supramolecular organic framework with permanent intrinsic porosity and tunable selectivity

by A. Chaix, G. Mouchaham, A. Shkurenko, P. Hoang, B. Moosa, P.M. Bhatt, K. Adil, K.N. Salama, M. Eddaoudi, N.M. Khashab

Year: 2018

Bibliography

A. Chaix, G. Mouchaham, A. Shkurenko, P. Hoang, B. Moosa, P.M. Bhatt, K. Adil, K.N. Salama, M. Eddaoudi, N.M. Khashab. Trianglamine-based supramolecular organic framework with permanent intrinsic porosity and tunable selectivity. Journal of the American Chemical Society 140 (44), 14571-14575, 2018

Abstract

Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO₂. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO₂/CH₄ separation for natural gas upgrading.

Pub_2018_TBS

Keywords

Carbon Dioxide Supramolecular Chemistry Porosity