C-Aminoimidoylation and C-Thiocarbamoylation of Esters, Sulfones, and Ketones

by Khashab, N. M., Haase, D. N., Yoshioka, M., Ghiviriga, I., Steel, P. J., Katritzky, A. R.

Year: 2007

Bibliography

Khashab, N. M.; Haase, D. N.; Yoshioka, M.; Ghiviriga, I.; Steel, P. J.; Katritzky, A. R. C-Aminoimidoylation and C-Thiocarbamoylation of Esters, Sulfones, and Ketones. J. Org. Chem. 2007, 72, 6742-6748

Abstract

Esters, sulfones, and ketones were C-aminoimidoylated and C-thiocarbamoylated by benzotriazole-1-carboxamidines and 1-(alkyl- or -arylthiocarbamoyl)benzotriazoles, resp. The present work represents the first systematic approach to these compd. classes, the few previously known examples of which were obtained by diverse approaches.

Keywords

C-aminoimidoylation C-thiocarbamoylation